Asrock 890GX Extreme3 moding NMVE BOOT

Can the bios be modded to boot from SSD M2 in slot PCI.
BIOS - 8Mb AMI Legal BIOS

On old AMI Core 8 bios only this option:

or using a Samsung 950 Pro (It has its own NVMe rom, no bios mod need)

Where should I look - PCI Vendor ID and Device ID